本科生毕业论文（设计）
题目氧化聚乙烯蜡乳液的制备及其应用性能学院轻纺与食品学院 专业轻化工程
学生姓名郑浩
tf2o学号0743092092年级2007
喷淋除尘器指导教师李正军
教务处制表
二0一一年六月五日
氧化聚乙烯蜡乳液的制备及其应用性能
指路器专业：轻化工程
学生：郑浩指导老师：李正军
摘要：首先采用相转变法乳化氧化聚乙烯蜡制得氧化聚乙烯蜡乳液，并检测乳液的粒径及分布，zeta 电位，存放稳定性，耐热稳定性，冻融稳定性和离心稳定性。考察了乳化剂种类、用量、HLB值、乳化温度、乳化时间、搅拌速度等主要因素对乳化效果的影响。结果表明，使用1300系列乳化剂和K12复配获得HLB值介于12.0到13.0的乳化体系，乳化剂用量为氧化聚乙烯蜡的30％，乳化温度为110℃，乳化时间为20min，搅拌速度为6000~8000r/min，可制备出稳定性好的氧化聚乙烯蜡乳液。然后将蜡乳液与聚氨酯乳液按不同配比复配成膜并检测涂膜的拒水性和透光率。最后，将蜡乳液和有机硅乳液复配后用于皮革涂饰，研究其对皮革涂层耐湿擦性、耐折性、手感、拒水性、离板性能的影响。结果表明，蜡乳液可以明显改善涂层的耐湿擦性、手感、拒水性、离板性等性能。 关键词：氧化聚乙烯蜡乳液乳化有机硅乳液复配涂饰
Preparation and Application Performances of
Oxidized Polyethylene Wax Emulsion
Chemical Engineering in Light Industry
盐酸环丙沙星凝胶Supervisor::Li Z hengjun Undergraduate：Zhenghao Supervisor
Abstract：First,the method of phase conversion was used to emulsify the oxidized polyethylene wax to prepare oxidized polyethylenelene wax emulsion,and test size and distribution,zeta potential,storage stability, heat stability,the stability of freeze-thaw stability and Centrifugal stability of the wax emulsion.the main factors which can effect the properties of wax emulsion mainly were studied including sorts of emulsifiers,the amount of emulsifiers,HLB value,the emulsifying temperature and sheared mixing speed.The experiment indicate that the steady and stable oxidized polyethylene wax emulsion can be prepared under following condition use1300and K12complex to get a HLB=12.0-13.0emulsifier system,the total amount of these emulsion systems is30％of wax mass,respectively,emulsion temperature is110℃,emulsion time is20min and continuously stirring speed is6000-8000r/min.Then complex the wax emulsion and polyurethane emulsion at different ratios and test water repellency and transmittance of the coating.Finally,complex wax emulsion and the silicone emulsion for leather finishing and study the effect of complex emulsion to coating performance in moisture wipping resistence,folding resistence,feel,water repellency and performance from the plate.The result shows that wax emulsion can apparently improve the moistur
e wipping resistence,feel, water repellency and performance from the plate and other performance of the leather coating.
Key words:Oxidation polyethylene wax emulsion emulsification polysiloxane emulsion formulation coating
符号说明
OPE氧化聚乙烯蜡
AEO-9脂肪醇聚氧乙烯醚1340异构十三醇聚氧乙烯醚1390异构十三醇聚氧乙烯醚K-12十二烷基硫酸钠
HLB表面活性剂亲水亲油平衡值PU聚氨酯
ES1聚醚硅油
ES2聚醚硅油
目录
1前言 (1)
1.1氧化聚乙烯蜡的研究概况 (1)
1.2水性聚氨酯树脂的研究概况 (2)
1.3论文思路与研究内容 (2)
1.4选题意义及目的 (3)
反垃圾邮件系统
2主要实验试剂及仪器 (3)
3OPE蜡的探索性实验 (4)
3.1OPE蜡乳液的制备 (4)
3.2结果与讨论 (5)
4制备XH-25蜡乳液 (5)
4.1实验方法 (5)
4.2氧化聚乙烯蜡乳液分析方法 (6)
4.3结果与讨论 (6)
4.3.1乳化剂选择、配方、用量对乳化效果的影响 (6)
4.3.2乳化时间及冷却方式对乳化效果的影响 (8)
4.3.3乳化温度对乳化效果的影响 (9)
4.4.4搅拌速度对乳化效果的影响 (9)
4.4.5助乳化剂对乳液性能的影响 (10)
4.4.6加料顺序及方式对乳液性能的影响 (10)
4.4小结 (11)
5氧化聚乙烯蜡乳液与PU树脂的复配成膜 (11)
5.1含有氧化聚乙烯蜡乳液的PU涂膜的制备方案 (11)
打棉机
5.2结果与讨论 (12)
6氧化聚乙烯蜡乳液用于皮革涂饰 (12)
6.1蜡乳液复配涂饰皮革方案 (12)
6.2皮革涂膜性能测试方法 (13)
6.3实验结果与讨论 (13)
6.3.1皮革涂层的耐湿擦性测试 (13)
6.3.2皮革涂层耐折性测试 (14)
6.3.3皮革涂层离板性能测试 (14)
6.3.4皮革涂层手感检验 (14)
6.3.5皮革涂层拒水性测试 (15)
